Product ID:KODAK 3000 FIXER AND REPLENISHER, KIT, PART B
MSDS Date:04/19/1995
FSC:6750
NIIN:00D004526
Kit Part:Y
MSDS Number: BZMZB

EASTMAN KODAK COMPANY

343 STATE STREET
ROCHESTER, NY 14650
US

Emergency Phone: 716-722-5151

Info Phone: 800- 242-2424

Cage: 19139

EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS

ROCHESTER, NY 14650-1115 US

Telephone: 716-722-5151/(800) 242-2424

Cage: 19139

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 70-75%

ALUMINUM SULFATE

CAS: 10043-01-3

RTECS: BD1700000

Fraction By Weight: 15-20%

OSHA PEL 2 MG/M3

ACGIH TLV: 2 MG/M3; 9596

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

SULFURIC ACID (SARA 302/313) (CERCLA)

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: <11%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3/3 STEL; 9596

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:ORAL LD50 (RAT) IS 0.5-5.0 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: EXPECTED TO BE LOW HAZARD
FOR RECOMMENDED HANDLING. EYES: CAUSES IRRITATION. SKIN: CAUSES
IRRITATION. INGESTION: HARMFUL IF SWALLOWED.
Explanation of Carcinogenicity:IARC HAS DETERMINED THAT EXPOSURE TO
STRONG INORGANIC MISTS/VAPORS CONTAINING SULFURIC ACID IS
CARCINOGENIC TO HUMANS.
Effects of Overexposure:MAY CAUSE BURNS OF THE GASTROINTESTINAL TRACT
IF SWALLOWED.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHALATION-IF SYMPTOMATIC, REMOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS PERSIST. EYES-IMMEDIATELY FLUSH WITH PLENTY
OF WATER FOR AT LEAST 15 MIN. GET MEDICAL ATTENTION.
SKIN-IMMEDIATELY REMO VE SOILED CLOTHES/SHOES & WASH WITH SOAP &
PLENTY OF WATER. GET MEDCIAL ATTENTION. INGESTED-DO NOT INDUCE
VOMITING. GIVE VICTIM A GLASS OF WATER. CALL A PHYSICIAN OR POISON
CONTROL CENTER IMMEDIATELY.

Flash Point:NONE
Extinguishing Media:USE APPROPIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:NONE.

Spill Release Procedures:NEUTRALIZE WITH SODIUM CARBONATE. FLUSH TO
SEWER WITH LARGE AMOUNTS OF WATER. OTHERWISE, ABSORB SPILL WITH
VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR
CHEMICAL WASTE. CLEAN SURF ACE THOROUGHLY TO REMOVE RESIDUAL
CONTAMINATION.
Neutralizing Agent:SODIUM CARBONATE.

Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP
AWAY FROM INCOMPATIBLE SUBSTANCES.
Other Precautions:AVOID CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT
BREATHE MIST OR VAPOR. USE WITH ADEUATE VENTILATION. WASH
THOROUGHLY AFTER HANDLING.

Respiratory Protection:NONE SHOULD BE NEEDED.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR)
SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS
Protective Gloves:IMPERVIOUS GLOVES SHOULD BE WORN.
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELD.
Other Protective Equipment:EYE BATH, SAFETY SHOWER, WASHING FACILITIES.
Work Hygienic Practices:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE SKIN CONTACT.
Supplemental Safety and Health
ECOLOGICAL INFORMATION: THIS MATERIAL IS STRONGLY ACIDIC AQUEOUS
SOLUTION, AND THIS PROPERTY MAY CAUSE ADVERSE ENVIRONMENTAL
EFFECTS.

HCC:C1
Boiling Pt:B.P. Text:212F,100C
Vapor Pres:18 MMHG
Vapor Density:0.6
Spec Gravity:1.32
pH:1.0
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID, YELLOW, SLIGHT SULFUR ODOR.
Percent Volatiles by Volume:71

Stability Indicator/Materials to Avoid:YES
BASES.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:SULFUR DIOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. NEUTRALIZE WITH SODIUM
CARBONATE. FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.